When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | HO2_Hochanadel(1972)_296K_190-260nm(W-rev).txt |
NAME: | hydroperoxy radical |
FORMULA: | HO2 |
AUTHOR(YEAR): | Hochanadel(1972) |
T: | 296K |
λ: | 190-260nm(W-rev) |
BIBLIOGRAPHY: |
C.J. Hochanadel, J.A. Ghormley, and P.J. Ogren, "Absorption spectrum and reaction kinetics of the HO2 radical in the gas phase",
J. Chem. Phys. 56, 4426-4432 (1972);
DOI: 10.1063/1.1677885
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COMMENTS: | Flash photolysis of H2O vapor (3%) in an atmosphere of H2, He or Ar containing ∼2% O2 W-rev = Wallington review Extinction coefficients have been read from Fig. 3, normalized to the value of σ(HO2) = 4.05×10-18 cm2 molecule-1 at 220 nm obtained in subsequent work
by Hochanadel et al. (1980), then converted to absorption cross sections, and reported by T.J. Wallington, P. Dagaut, and M.J. Kurylo, "Ultraviolet absorption cross sections and reaction kinetics and mechanisms for peroxy radicals in the gas phase," Chem. Rev. 92, 667-710 (1992); DOI: 10.1021/cr00012a008 |
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